Ethanol as a renewable fuel has been applied in fuel vehicles (FVs), and it is promising in hybrid electric vehicles (HEVs). This work aims to investigate the emission characteristics of ethanol applied in both FVs and plug-in hybrid electric vehicles (PHEVs). The paper conducted a real-road test of an internal combustion FV and PHEV, respectively, based on the world light vehicle test cycle (WLTC) by using gasoline and regular gasoline under different temperature conditions. The use of E10 and E20 in FVs has been effective in reducing the conventional emissions of the vehicles. At 23 ◦C, E10 and E20 reduced the conventional emissions including carbon monoxide (CO), total hydrocarbon compound (THC), non-methane hydrocarbon compound (NMHC), particulate matter (PM), and particulate number (PN) by 15.40–31.11% and 11.00–44.13% respectively. At 6 ◦C, E10 and E20 reduced conventional emissions including THC, CO, and PM by 2.15–8.61% and 11.02–13.34%, respectively. However, nitrogen oxide (NOX) emissions increased to varying degrees. The reduction trend of non-conventional emissions including methane (CH4), nitrous oxide (N2O), and carbon dioxide (CO2) from FVs fueled with E10 and E20 is not significant for vehicles. Overall, the emission reduction effect of E20 is better than that of E10, and the emission reduction effect of ethanol gasoline on vehicle emissions is reduced at low temperatures. Lower ambient temperatures increase vehicle emissions in the low-speed segment but decrease vehicle emissions in the ultra-highspeed segment. HEV emissions of THC, CO, PN, and PM are reduced by 25.28%, 12.72%, 77.34%, and 64.59%, respectively, for E20 compared to gasoline, and the use of E20 in HEVs contributes to the reduction of overall vehicle emissions.
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