In this study, five fuels including pure diesel (B0), pure palm oil biodiesel (B100), and their blends (B10, B20, and B30) were investigated in relation to soot particle distribution and regulated and unregulated emission characteristics in a common rail direct injection (CRDI) diesel engine. The results indicated that CO, hydrocarbon (HC), and particulate matter (PM) regulated emissions were effectively controlled to a very low level by combining the addition of palm oil biodiesel (POB) to diesel with optimized engine operating conditions. Paper filters and TEM grids were used to capture the diesel particles. All the PM primary particles were less than 100 nm in diameter observed by TEM, and the average diameters of the PM primary particles for the biodiesel blends were distributed between 20 and 26 nm. Unregulated emissions such as trace metals including Pb, Mn, and Ba were found in the PM particles, and the xylene, toluene, and benzene unregulated emissions of B100 were reduced by 55.68%, 21.56%, and 18.32%, respectively, compared to those of B0. Therefore, POB is an excellent alternative fuel for diesel engines and has great application potential to solve the current pollution problems of regulated and unregulated emissions.
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