At present, the common cooking fume purification devices are mostly based on electrostatic technology. There are few researches on the microscopic process of coalescence and electric field parameters’ optimization. In this paper, COMSOL MultiphysicsTM was used to simulate the electrostatic coalescence of oil droplets in the coupling field of an electric field and flow field. The degree of deformation of oil droplets (D) and the starting coalescence time (tsc) were used to evaluate the coalescence process. The feasibility of the model was verified through experimental results. The effects of voltage, flow speed and oil droplet radius on tsc were investigated, and the parameters were optimized by the response surface method and Matrix correlation analysis. It can be concluded that increasing the voltage, flow speed and oil droplet radius appropriately would be conducive to the coalescence of oil droplets. When the oil droplet radius was in the range of 0–1.5 mm, it promoted the coalescence of oil droplets. The influence of various factors on oil droplet coalescence was flow speed > voltage > oil droplet radius. The optimal result obtained by simulation was that when the radius of the oil droplet was 1.56 mm, the voltage 12 kV and the flow speed 180 mm/ms, the shortest coalescence time of oil droplets was 16.8253 ms.
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