Current Issue : January-March Volume : 2022 Issue Number : 1 Articles : 5 Articles
The overrunning disaster of harmful gas tends to occur in the working face in thick coal seam with high gas concentration, as the fully mechanized caving stope has the characteristics of high mining intensity, high remnant coal, and high gas content. Therefore, the disastrous mechanism and concentration distribution of gas migration in fully mechanized caving stope are the theoretical basis for gas control scheme. Based on the 7607 working face in Wuyang coal mine, the gas emission quantity in working face is comprehensively analyzed by field measurement in this paper. The gas leakage field, oxygen concentration field, and gas concentration field in 7607 working face are simulated by establishing the equal proportional numerical model. Due to the increase of air leakage in working face caused by the high alley pumping drainage, the risk of coal spontaneous combustion is also analyzed, when gas extraction in goaf is carried out. The research results show that the gas drainage technology in high drainage roadway has a remarkable effect on the gas overrunning phenomenon. The gas concentration near the upper corner of the working surface has been reduced from 0.7%-1% to 0.5%. At the same time, it is necessary to pay attention to the risk of coal spontaneous combustion in the goaf for gas drainage in the high drainage roadway. The width of the oxidation zone in the goaf is about 25m deeper than that before the drainage. Research results provide the references for gas control technology and coal spontaneous combustion prevention in similar working faces....
Field measured PAH emissions from diverse sources in China are limited or even not available. In this study, the PM2.5-bound PAH emission factors (EFs) for typical biomass and coal combustion in China were determined on-site. The measured total PAH EFs were 24.5 mg/kg for household coal burning, 10.5–13.9 mg/kg for household biofuel burning, 8.1–8.6 mg/kg for biomass open burning, and 0.021–0.31 mg/kg for coal-fired boilers, respectively. These EF values were compared with previous studies. The sources profiles of PAHs for four sources were developed to use in chemical mass balance receptor modelling. BaP equivalent EFs (EFBaPeq) were calculated to evaluate PAH emission toxicity among different combustion sources, and were 6.81, 2.94–4.22, 1.59–3.62, and 0.0006–0.042 mg/kg for those four types of sources, respectively....
In this study, we develop a fully coupled thermal-hydrological-mechanical-chemical (THMC) model to analyze the spontaneous combustion process of underground coal seams, focusing on investigating the influences of the pressure difference between oxygen and coal, the rate of coal-oxygen reaction heat, and the activation energy. The simulation results show that as oxygen propagates into the coal seams, the coal-oxygen reaction causes the spontaneous combustion of coal to heat. The consumption of oxygen leads to an increase in oxygen consumption along the way and a decrease in gas pressure. The permeability near the right boundary increases while significantly reducing the area far away from the right boundary as the predominant effect of spontaneous combustion. Additionally, a sensitivity study shows that a more considerable pressure difference and coal-oxygen reaction heat contribute to promoting the coal temperature, while the activation energy has a slight effect. Moreover, an increase in coal-oxygen reaction heat and activation energy accelerates the oxygen consumption rate and thus causes a lower oxygen concentration. Overall, the results provide a basis for the prediction and prevention of coal seam spontaneous combustion....
During a severe accident in a nuclear power plant, hydrogen can be generated, leading to risks of possible deflagration and containment integrity failure. To manage severe accidents, great experimental, analytical, and benchmarking efforts are being made to understand combustible gas distribution, deflagration, and detonation processes. In one of the benchmarks—SARNET H2—flame acceleration due to obstacle-induced turbulence was investigated in the ENACCEF facility. The turbulent combustion problem is overly complex because it involves coupling between fluid dynamics, mass/heat transfer, and chemistry. There are still unknowns in understanding the mechanisms of turbulent flame propagation, therefore many methods in interpreting combustion and turbulent speed are present. Based on SARNET H2 benchmark results, a two-dimensional computational fluid dynamics simulation of turbulent hydrogen flame propagation in the ENACCEF facility was performed. Four combustible mixtures with different diluents concentrations were considered—13% H2 and 0%/10%/20%/30% of diluents in air. The aim of this numerical simulation was to validate the custom-built turbulent combustion OpenFOAM solver based on the progress variable model—flameFoam. Furthermore, another objective was to perform parametric analysis in relation to turbulent speed correlations and turbulence models and interpret the k-! SST model blending function F1 behavior during the combustion process. The obtained results show that in the simulated case all three turbulent speed correlations behave similarly and can be used to reproduce observable flame speed; also, the k-" model provides more accurate results than the k-! SST turbulence model. It is shown in the paper that the k-! SST model misinterprets the sudden parameter gradients resulting from turbulent combustion....
Perovskite-like solid solution La0.5Ca0.5Mn0.5Co0.5O3 was tested during the total methane combustion reaction. During the reaction, there is a noticeable decrease in methane conversion, the rate of catalyst deactivation increasing with an increase in temperature. The in situ XRD and HRTEM methods show that the observed deactivation occurs as a result of the segregation of calcite and cobalt oxide particles on the perovskite surface. According to the TGA, the observed drop in catalytic activity is also associated with a large loss of oxygen from the perovskite structure....
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